SECRETARY'S SPLIT WITH PRESIDENT LONG IN MAKING
A working lunch of the National Security Council had just adjourned in the Cabinet Room of the White House early Friday afternoon when President Reagan said to Secretary of State Alexander M. Haig Jr., ''Al, may I see you for a moment?'' It was then, according to White House aides, that a stunned Secretary Haig learned that his offer to resign, made the day before, had been accepted, and that Mr. Reagan had selected George P. Shultz, a former Treasury Secretary, to replace him. Later in the afternoon, it was Mr. Haig who in turn stunned Mr. Reagan and his staff members by putting into his resignation letter a parting blast at the Administration. In recent months, Mr. Haig said, foreign policy had shifted from the ''careful course'' originally established by the President and himself.